Making [1.1.1]Propellane
Chemiolis Chemiolis
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 Published On Apr 27, 2023

Mr. Explosions&Fire Extractions&Ire aka Australian man aka Tom has been playing Minecraft for 3 years straight. It is time to stop him.

In this video I am making [1.1.1]Propellane starting with the chlorination of Pentaerythritol, followed by alcohol oxidation and decarboxylation. The resulting terminal alkene is then reacted with the dibromo carbene which is formed from Bromoform. The resulting dibromo dichloro product is then subjected to a double transmetalation with methyllithium to form [1.1.1]Propellane.

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