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"Nothing's Gonna Stop Us Now" by Starship. It's a power ballad that was released in 1987 and became one of Starship's biggest hits. The song was featured in the soundtrack of the romantic comedy film "Mannequin." "Nothing's Gonna Stop Us Now" is known for its uplifting and romantic lyrics, making it a popular choice for weddings and other special occasions. The lead vocals are performed by Grace Slick and Mickey Thomas.